System Information
Operating system: Windows 10
Graphics card: NVIDIA Geforce GTX 1060 3 GB
Blender Version
2.83.2
Short description of error
Sampling in Vertex mode samples the color in the view port while the sampler in Texture Paint samples the original color of the image texture.
It's more constructive to have the vertex paint mode sample the actual vertex color.
Exact steps for others to reproduce the error
With Eevee active, Paint Vertex colors on an object and press S and notice the color it samples is from the Eevee material.